Photoisomerization of cis,cis-1,4-diphenyl-1,3-butadiene in glassy media at 77 K: the bicycle-pedal mechanism.
نویسندگان
چکیده
The cis-trans photoisomerization of cis,cis-1,4-diphenyl-1,3-butadiene in a soft isopentane glass at 77 K gives significant two-bond photoisomerization in contrast to solution and hard glassy media where only one-bond photoisomerization takes place.
منابع مشابه
Bicycle pedal photoisomerization of 1-phenyl-4-(4-pyridyl)-1,3-butadienes in glassy isopentane at 77 K.
In glassy isopentane at 77 K, 1-phenyl-4-(4-pyridyl)-cis-1,cis-3-butadiene (cc-PPyB) and 1-phenyl-4-(4-pyridyl)-cis-1,trans-3-butadiene (ct-PPyB) can undergo simultaneous two-bond photoisomerization. Under the same conditions, 1-phenyl-4-(4-pyridyl)-trans-1,cis-3-butadiene (tc-PPyB) gives tt-PPyB, the ultimate photoproduct in all cases.
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ورودعنوان ژورنال:
- Chemical communications
دوره 14 شماره
صفحات -
تاریخ انتشار 2006